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That is a very difficult question to answer. Much like Modern English is to Middle/Old English, Modern Greek's orthography is based on Ancient Greek, and therefore, like English, its pronunciation differs greatly from its spelling. There are some "rules" for the "i" sound and "omicron" versus "omega". If I have counted correctly there are 5 "i" sounds and two "o" sounds in Modern Greek. So, this might take a while.
[First, let me start out, that the following rules do not apply to the "i" sound at the beginning or inside a word, but only to ending of a word.]
1) the "eta" (Η/η) is the nominative article for the feminine singular, e.g. η καρέκλα, η πόρτα, κτλ.
a) It is also the ending for nominative feminine words, such as:
η πόλη, η πρόταση, κτλ.
b) to a much lesser extent, the neuter pl.
e.g. το μέρος ---> τα μέρη
2) the "iota" (Ι/ι) can be the ending for the nominative/accusative (objective) neuter singular
so: το σπίτι, το ταβάνι, το κουτί, κτλ.
3) The "upsilon" (Υ/υ) can also be an ending for the nominative/accusative (objective) neuter singular
E.g. το βράδυ, το δάκρυ, κτλ.
4) The digraph, which is one sound written with two letters, (once a dipthong, which is two sounds crammed together, in Ancient Greek) Omicron-Iota (ΟΙ/οι) can either be:
a) The masculine/feminine nominative plural article
e.g. οι πόρτες (f.); οι άνθρωποι (m.).
b) it can also be the ending of the nominative plural masculine
e.g. οι άνθρωποι, οι κύποι, κτλ.
5) the digraph (once a dipthong in Ancient Greek) Epsilon-Iota (ΕΙ/ει) is, as an ending, reserved for the 3rd sing. of verbs
e.g. αγοράζει (he/she/it buys); έχει (he/she/it has)
Again, these "rules" only apply to the endings of Modern Greek words.
To solve your Omicron/Omega problem:
1) Omicron, as an ending, is used for
a) the singular ending of the nominative/accusative neuter
e.g.
το βιβλίο είναι κακό (the book is bad) [Subj.]
Βλέπω το βιβλίο (I see the book) [Obj.]
b) the accusative masculine singular
e.g. Βλέπω τον άνθρωπο (I see the person)
2) The Omega (Ω/ω), as an ending is:
a) primarily used as the 1st Sing. of Verbs
e.g. Βλέπω (I see), Κάνω (I do), Έχω (I have)
vs. Βλέπεις (You see), Κάνει (He/she it does), Έχουν (they have)
b) to a much lesser extent, the feminine nom./acc. (obj.) ending.
c) and very rarely, with certain fixed phrases, the omega can be an old dative:
δόξα τω Θεώ "Thanks to God".
There are more differences and distinctions, but these are the ones that come to me off-hand. Again, these rules only apply to the ENDINGS of Greek Words. It takes a long time getting used to. (I can barely spell in English, and it's my NATIVE language). If you want something more comprehensive, a Modern Greek Grammar will give you all the uses of the various "i"'s and "o"'s of Modern Greek.
Αδάμ
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